期刊
TETRAHEDRON LETTERS
卷 51, 期 10, 页码 1371-1373出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2009.12.140
关键词
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Highly enantio-enriched perfluoroalkyl amines are shown to be synthesized by perfluororalkylation and asymmetric reduction of nitriles. Perfluoroalkylation of nitriles can be attained by the Lewis acidic perfluoroalkyl titanate reagents to give acyclic ketimines. Catalytic asymmetric hydrogenation of the acyclic ketimines affords the perfluoroalkyl amine products in up to 93% ee. (C) 2010 Elsevier Ltd. All rights reserved.
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