期刊
TETRAHEDRON LETTERS
卷 51, 期 50, 页码 6608-6610出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2010.10.052
关键词
-
资金
- EPSRC
- University of Sheffield
A mild method for the generation of benzynes from 2-(trimethylsilyl)iodobenzene derivatives is reported. The employment of silver fluoride in conjunction with caesium fluoride is key for promoting useful levels of elimination and providing benzyne derived products in good yields. Moreover, the substrates are accessed by a novel alkynyl iodide cycloaddition. (C) 2010 Elsevier Ltd. All rights reserved.
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