期刊
TETRAHEDRON LETTERS
卷 51, 期 38, 页码 4959-4961出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2010.07.048
关键词
Rhodium; Hydroaminomethylation; Tetrahydroquinoline; Benzazepine
资金
- Natural Sciences and Engineering Council of Canada (NSERC)
Ionic diamine rhodium complexes catalyze the hydroaminomethylation of 2-allylanilines. The reaction involves initial hydroformylation followed by reductive amination, which provides direct access to 1,2,3,4-tetrahydroquinolines and 2,3,4,5-1H-1-benzazepines. (C) 2010 Elsevier Ltd. All rights reserved.
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