期刊
TETRAHEDRON LETTERS
卷 50, 期 19, 页码 2200-2203出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2009.02.151
关键词
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资金
- National Natural Science Foundation of China [20632060, 20532050]
- Chinese Academy of Sciences
- Major Basic Research Development Program of China [2006CB806106]
- Science and Technology Commission of Shanghai Municipality
- Merck Research Laboratories
A class of chiral self-supported catalysts prepared from bis-BINOL ligands and diethyl zinc were successfully applied in the hetereogeneous enantioselective epoxidation of a range of (E)-alpha,beta-unsaturated ketones, affording the corresponding epoxy ketones in high enantioselectivity. The self-supported catalysts were easily recovered from the reaction mixture and were reusable for several consecutive runs. (C) 2009 Elsevier Ltd. All rights reserved.
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