期刊
TETRAHEDRON LETTERS
卷 50, 期 28, 页码 4141-4144出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2009.04.130
关键词
Isomerization; Allylic alcohols; Iridium; P,N-Ligands
资金
- University of Geneva
The isomerization of primary allylic alcohols into the corresponding aldehydes has been accomplished using an analogue of Crabtree's iridium hydrogenation catalyst and by adequately tuning the experimental conditions. A wide range of substrates is converted quantitatively into the desired aldehyde at room temperature in expedient reaction times by using catalyst loading as low as 0.25 mol %. (C) 2009 Elsevier Ltd. All rights reserved.
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