期刊
TETRAHEDRON LETTERS
卷 50, 期 32, 页码 4624-4628出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2009.05.100
关键词
-
资金
- National Natural Science Foundation of China [20772124]
- National Basic Research Program of China [2009CB825300]
Transfer hydrogenation (TH) of ketones and aldehydes was efficiently carried out in 2-propanol at room temperature by means of a ruthenium(II) complex catalyst bearing a 2-(benzoimidazol-2-yl)-6-(pyrazol-1-yl)pyridine ligand. TH of the ketone substrates proceeded in air, reaching final TOFs of up to 59,400 h(-1), and the reduction of aldehydes proceeded under a nitrogen atmosphere to achieve final TOFs of up to 5940 h(-1). (C) 2009 Elsevier Ltd. All rights reserved.
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