期刊
TETRAHEDRON LETTERS
卷 50, 期 38, 页码 5424-5427出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2009.07.063
关键词
Fluoroalkenes; Radical reactions; Vinyl sulfides; alpha-Fluoro vinyl sulfides; Vinyl sulfones
资金
- NIGMS [SC1CA138176]
- NCI
- MBRS RISE [R25 GM61347]
Radical-mediated thiodesulfonylation of the vinyl and (alpha-fluoro)vinyl sulfones, derived from aldehydes and ketones, with aryl thiols in organic or aqueous medium provided access to vinyl and (a-fluoro)vinyl sulfides. The vinyl sulfides were formed predominantly with E stereochemistry independent of the stereochemistry of the starting vinyl sulfones. (C) 2009 Elsevier Ltd. All rights reserved.
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