期刊
TETRAHEDRON LETTERS
卷 50, 期 1, 页码 81-84出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2008.10.090
关键词
Ferrier rearrangement; Glucal; Isocyanides; C-Glycosyl amides
资金
- UGC, New Delhi
Glycals undergo smooth carbon-Ferrier rearrangement with isocyanides in the presence of a catalytic amount of FeCl3 under mild reaction conditions to provide C-glycosyl amides in good yields with high alpha-selectivity. The use of FeCl3 makes this method simple, convenient and cost-effective. This is the first report on carbon-Ferrier rearrangement using isonitriles as nucleophiles. (C) 2008 Elsevier Ltd. All rights reserved.
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