期刊
TETRAHEDRON LETTERS
卷 49, 期 48, 页码 6924-6928出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2008.09.108
关键词
Baylis-Hillman adduct; Bicyclo[3.1.0]; S(N)2-type reductive elimination; C-C bond formation; Cyclization-oxidation
资金
- ECUST
Cyclization-oxidation of Baylis-Hillman adducts provides a convenient method to stereoselectively synthesize variety of multi-substituted bicyclo[3.1.0] ring systems via Pd(II)/Pd(IV)-catalyzed reactions. We also disclose that C-Pd(IV) intermediate can undergo reductive elimination through S(N)2-type attack by the latent nucleophile of vinyl acetate to afford C-sp3-C-sp3 bond formation with inversion of configuration at the Pd(IV)-bounded carbon. (C) 2008 Elsevier Ltd. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据