期刊
TETRAHEDRON
卷 70, 期 45, 页码 8681-8689出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2014.09.038
关键词
Iridium; Cycloaddition; Alkyne; Alkynyl ketone; Alkynyl ester
资金
- Japan Society for the Promotion of Science [25410119]
- Ministry of Education, Culture, Sports, Science, and Technology of Japan
We found that the combination of [Ir(cod)Cl](2) and rac-BINAP served as an efficient catalyst for the [2+2+2] cycloaddition of 2,7-nonadiyne derivatives and related compounds with alkynyl ketones and alkynyl esters. The corresponding products were obtained in high yields under mild reaction conditions. (C) 2014 Elsevier Ltd. All rights reserved.
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