4.4 Article

Palladium-catalyzed direct ortho-acylation through an oxidative coupling of 2-arylbenzothiazoles with benzylic alcohols

期刊

TETRAHEDRON
卷 69, 期 41, 页码 8661-8667

出版社

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2013.08.005

关键词

ortho-Acylation; 2-Arylbenzothiazoles; Benzylic alcohols; tert-Butyl hydroperoxide

资金

  1. National Natural Science Foundation of China [21002042]
  2. Jiangxi Educational Committee [GJJ12169]
  3. Open Project Program of Key Laboratory of Functional Small Organic Molecule, Ministry of Education, Jiangxi Normal University [KLFS-KF-201217]

向作者/读者索取更多资源

An efficient protocol was developed for Pd-catalyzed direct C H bond acylation by cross-dehydrogenative-coupling of arylbenzothiazoles and benzylic alcohols using tert-butyl hydroperoxide (TBHP) as the oxidant. The acylation reactions exhibit good reactivities and excellent regioselectivity. (C) 2013 Elsevier Ltd. All rights reserved.

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