期刊
TETRAHEDRON
卷 69, 期 35, 页码 7264-7268出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2013.06.083
关键词
Cobalt complex; Carbonylation; Phenylacetic acid derivatives; Scale-up experiment; Theoretical computation
资金
- National Natural Science Foundation of China (NSFC) [20972124, 21272184, 21143010]
- Shaanxi Provincial Natural Science Fund Project [2012JQ2007]
- Shaanxi Science and Technology Co-ordination Innovation Engineering Project [2011K12-77]
- Special Science Research Foundation of Education Committee in Shaanxi Province [12JK0584]
- Xi'an City Science and Technology Project [CXY1123-1]
A highly efficient cobalt-catalyzed carbonylative approach to phenylacetic acid derivatives under one atmosphere pressure is reported. This methodology represents a useful extension of benzimidazole used as ligand in metal catalysis, and the catalytic mechanism has been proved by computer simulation. Notably, this new cobalt precatalyst, which promotes the carbonylation reaction dramatically and has already been used for scale-up experiment of phenylacetic acid derivatives. (C) 2013 Elsevier Ltd. All rights reserved.
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