期刊
TETRAHEDRON
卷 69, 期 29, 页码 5920-5926出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2013.05.006
关键词
Fluorine; Radical; Difluoromethyl; Phosphorus; Acetate
资金
- CNRS
- Ministere de l'ensignement superieur et de la recherche
- Crunch Network (interregional organic chemistry network Region Basse-Normandie)
The ambiphilic character of fluorinated radicals was noticed during their radical conjugate addition onto electron-deficient alkenes. Free radicals were trapped with enones when the reaction was conducted from iododifluoro-acetate and -phosphonate derivatives in the presence of Et3B. Competitive addition reaction onto electron-rich or -deficient alkenes was observed depending on the free radical initiator. (C) 2013 Elsevier Ltd. All rights reserved.
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