期刊
TETRAHEDRON
卷 68, 期 46, 页码 9413-9418出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2012.09.010
关键词
Allylation; Iridium; Phosphoramidite ligand; Sodium 2-aminobenzenethiolate; Benzo-fused N,S-heterocycle
资金
- Pu Jiang Program of Shanghai
- NSFC [21272175]
- State Key Laboratory of Fine Chemicals, Dalian University of Technology [KF1006]
The use of sodium 2-aminobenzenethiolate in the enantioselective iridium catalyzed allylic substitution with a range of methyl allyl carbonates allows the concise synthesis of the branch-type products with both excellent regio- and enantioselectivities, which are functionalized N,S-containing allylic intermediates for the formation of chiral benzo-fused N,S-heterocycles. (C) 2012 Elsevier Ltd. All rights reserved.
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