期刊
TETRAHEDRON
卷 68, 期 40, 页码 8424-8430出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2012.07.089
关键词
Bronsted acid; Heterogeneous catalysis; Recycling; Quinones; Heterocyclic compd; Fluoroalcohol
资金
- JSPS
- MEXT
- Ritsumeikan Global Innovation Research Organization (R-GIRO) project
- Asahi Glass Foundation
- Industrial Technology Research Grant Program from NEDO of Japan
- Grants-in-Aid for Scientific Research [24689002] Funding Source: KAKEN
Controlled couplings of quinone monoacetals 1 with soft nucelophiles have been achieved using a new and reusable perfluorobenzoic acid (PFBA) immobilized on polystyrene beads as an efficient polymer-anchored specific proton. Various advantages regarding the recovery, reusability, and reproducibility as well as the high chemoselectivity toward quinone monoacetals 1 have been determined as the key features of the cleaner systems with newly developed solid acid promoter for the reactions. (C) 2012 Elsevier Ltd. All rights reserved.
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