期刊
TETRAHEDRON
卷 68, 期 22, 页码 4233-4241出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2012.03.091
关键词
-
资金
- National Natural Science Foundation of China [21172166]
- Natural Science Foundation of Zhejiang Province [Y4100783]
Practical and straightforward method for regioselective C-S bond formation accomplished by copper-catalyzed regioselective C-F substitution of electron-deficient perfluoroarenes with aryl thioacetates or benzyl thioacetate has been developed. Because of its high reaction efficiency, good chemoselectivity and regioselectivity, and excellent functional-group compatibility, this protocol provides a useful and operationally simple access to polyfluoroaryl thioethers used for drugs and material chemistry. (C) 2012 Elsevier Ltd. All rights reserved.
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