期刊
TETRAHEDRON
卷 67, 期 14, 页码 2536-2541出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2011.02.031
关键词
Organocatalysis; Piperidine motif; L-(-)-733061; (25,3S)-Methyl 3-aminopiperidine-2-carboxylate; aza-Henry reaction; Febrifugine; Glycosidase inhibitors
资金
- DST, New Delhi, India [SR/SI/OC-12/2007]
- UGC (New Delhi)
An efficient enantioselective synthesis of L-(-)-733,061 and (2S,3S)-methyl 3-aminopiperidine-2-carboxylate is accomplished by means of catalytic enantioselective aza-Henry reaction. A key feature of this protocol is organocatalysis as genesis of chirality to ensure high degree of distereo- and enantiocontrol. (C) 2011 Elsevier Ltd. All rights reserved.
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