期刊
TETRAHEDRON
卷 67, 期 10, 页码 1971-1976出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2010.12.070
关键词
-
资金
- Fond Unique Interministeriel 'REDSUP'
The system 1,1,3,3-tetramethyldisiloxane (TMDS)/Fe(acac)(3) is reported here as a new method to obtain amines from aromatic nitro compounds. Amines are synthetized in a straightforward step and are isolated as hydrochloride salts with good to excellent yields. This system has shown a good selectivity toward aryl-chloride, aryl-bromide, ester, carboxylic acid, and cyano groups. The reduction of alkylnitro compounds was unfortunately not possible using this method, only a mixture of mono and dialkylated amine was obtained. (C) 2011 Elsevier Ltd. All rights reserved.
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