期刊
TETRAHEDRON
卷 67, 期 49, 页码 9622-9626出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2011.09.002
关键词
Grubbs carbene complex; Catalytic reaction; Marine huge molecule; Degradation reaction
资金
- JSPS [16GS0206]
- Nagoya University from the Ministry of Education, Science, Sports and Culture, Japan
- Grants-in-Aid for Scientific Research [22603008, 16GS0206, 21221009] Funding Source: KAKEN
An oxidative cleavage of allyl vic-diols to aldehydes catalyzed by a Grubbs carbene complex using a co-oxidant has been established for the first time, with good yields. The utility of this selective cleavage reaction was demonstrated through the use of two huge marine molecules, symbiodinolide and N-p-BrBz palytoxin. (C) 2011 Elsevier Ltd. All rights reserved.
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