期刊
TETRAHEDRON
卷 67, 期 26, 页码 4862-4868出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2011.05.005
关键词
C-3-Symmetry; Imidazoline; Organocatalyst; Asymmetric reaction
资金
- JSPS
- Grants-in-Aid for Scientific Research [23790011] Funding Source: KAKEN
We describe the necessity of the C-3-symmetry and the role of a third imidazoline of trisimidazoline 3, which was recently developed by us as a new entry of organocatalyst. The utility of 3 as a Bronsted base catalyst in the nitro Michael reaction and the alpha-amination of beta-ketoesters was shown, and the re-cyclability of the catalyst was also demonstrated. (C) 2011 Elsevier Ltd. All rights reserved.
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