期刊
TETRAHEDRON
卷 66, 期 13, 页码 2439-2443出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2010.01.085
关键词
Enantioselective organocatalysis; Intramolecular Morita-Baylis-Hillman reaction; Chiral phosphinothiourea; Amino acids; Enones
资金
- National Natural Science Foundation of China [20772029]
- Program for New Century Excellent Talents in University [NCET-07-0286]
A series of chiral bifunctional phosphinothioureas derived from L-amino acids have been developed to promote the enantioselective intramolecular Morita-Baylis-Hillman reaction. The process afforded the cyclic hydroxyl enones with up to 84% ee and good yields under mild conditions. (C) 2010 Elsevier Ltd. All rights reserved.
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