期刊
TETRAHEDRON
卷 66, 期 31, 页码 5768-5774出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2010.04.087
关键词
Polyvalent organoiodine compounds; Iodyl benzene; Iodoxybenzene; Iodosylbezene
资金
- Petroleum Research Fund
The synthesis and characterization of new hypervalent iodine reagents ArINTs (2a), ArIO (3a), and ArIO(2) (4a) (Ar=2-tert-butylsulfonyl-5-tert-butylphenyl) are described. These reagents are compared to previously reported analogous set of reagents Ar=2-tert-butylsulfonylphenyl and found to have significantly enhanced solubility and similar chemical reactivity. The X-ray crystal structures of 4a and of ArI (1a) (Ar=2-tert-butylsulfonyl-5-tert-butylphenyl) are discussed and compared. These reagents find use in atom and group transfer reactions. (C) 2010 Elsevier Ltd. All rights reserved.
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