期刊
TETRAHEDRON
卷 65, 期 34, 页码 6888-6902出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2009.06.078
关键词
Nucleophilic vinylic substitution; Sulfur-containing heterocycles; SNV sigma and SNV pi mechanisms; Density functional theory (DFT)
资金
- Nanyang Technological University
This article presents a full account of intramolecular vinylic substitution reactions of bromoalkenes having an acetylthio moiety, which give sulfur-containing heterocycles such as dihydrothiophene, tetrahydrothiopyran, and 2-alkylidenethietane derivatives. The reaction pathways of the substitution reactions were investigated by theoretical and experimental studies. (C) 2009 Elsevier Ltd. All rights reserved.
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