期刊
TETRAHEDRON
卷 65, 期 5, 页码 1059-1062出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2008.11.051
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资金
- Japan Society for the Promotion of Science
- Japan Society for the Promotion of Science (JSPS)
The first asymmetric total synthesis of prianosin B (1) is described. Formation of the 16,17-dehydropyrroloiminoquinone skeleton from the pyrroloiminoquinone unit is a key step in this synthesis. Thus, the detosylation and dehydrogenation reactions of the pyrroloiminoquinone unit are Caused by the presence of a catalytic amount of NaN3. (C) 2008 Elsevier Ltd. All rights reserved.
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