期刊
TETRAHEDRON
卷 65, 期 9, 页码 1919-1927出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2008.12.058
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Five different furfural derivatives were converted to chiral cyanohydrins by enzyme catalysis in good enantiomeric excess. After a sequence of silyl protection, nitrile reduction, tosylation and propargylation, Substrates for the gold(I) catalyzed cycloisomerization of delta-alkynyl furans delivered good yields of enantiomerically pure dihydroxytetrahydroisoquinoline building blocks. Neither racemization nor elimination to quinolines was observed. (C) 2008 Elsevier Ltd. All rights reserved.
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