期刊
TETRAHEDRON
卷 64, 期 5, 页码 809-820出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2007.09.087
关键词
ring-closing metathesis; furan; pyrrole; arenes; catalysis
资金
- Engineering and Physical Sciences Research Council [EP/C514866/1] Funding Source: researchfish
A range of differentially functionalised furans and pyrroles have been synthesised in short order by the judicious use of a ring-closing metathesis/aromatisation strategy. Two contrasting approaches are described exploiting a palladium-catalysed union of allylic alcohols and sulfonamides in one case, and a titanium mediated methylenation of homoallylic esters in another. A number of groups that are difficult to install via traditional methods were incorporated successfully. (c) 2007 Elsevier Ltd. All rights reserved.
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