期刊
SYNTHETIC COMMUNICATIONS
卷 44, 期 5, 页码 610-619出版社
TAYLOR & FRANCIS INC
DOI: 10.1080/00397911.2013.827207
关键词
Alcohol oxidation; molecular oxygen; NOx; sol-gel; TEMPO
资金
- Program for Changjiang Scholars and Innovative Research Team in University [IRT0711]
Silica-supported 4-OH-2,2,6,6-tetramethylpiperidyl-1-oxy/NOx (4-OH-TEMPO was immobilized on the surface of silica using the sol-gel method, and then it adsorbed NOx), as a heterogeneous catalyst, has exhibited good catalytic performance in alcohol oxidation. A broad range of alcohols were oxidized to their corresponding aldehydes or ketones with more than 99% selectivity and 99% conversion rate by such a catalyst system at room temperature in air. NOx not only acted as an electron bridge between O-2 and 4-OH-TEMPO but also were conducive to the formation of the aldehydes as active component. A possible mechanism for oxidation of alcohols promoted by silica-supported 4-OH-TEMPO/NOx was supposed. [Supplementary materials are available for this article. Go to the publisher's online edition of Synthetic Communications (R) for the following free supplemental resource(s): Full experimental and spectral details.]
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据