期刊
SYNTHESIS-STUTTGART
卷 51, 期 2, 页码 545-551出版社
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0037-1610295
关键词
copper(I) iodide; ligands; thiolation; pyrroles; indoles
资金
- National Natural Science Foundation of China [21102104, 21502065]
- Natural Science Foundation of Zhejiang Province [LY14B020011, LR15B020002]
A novel and convenient copper(I)-catalyzed thiolation of C-H bonds of pyrroles and indoles is developed for the synthesis of sulfenyl pyrroles and indoles. Dual C-H thiolation reactions are observed for pyrroles. A wide range of pyrroles and indoles undergo the C-H thiolation smoothly with various disulfides and diselenides to generate the corresponding heteroaryl thioethers in moderate to excellent yields.
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