期刊
SYNTHESIS-STUTTGART
卷 46, 期 3, 页码 281-289出版社
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0033-1338579
关键词
halomaleic anhydride; halomaleimide; metal-catalyzed cross-coupling; bioactive natural and unnatural products; synthesis
资金
- CSIR, New Delhi
- Department of Science and Technology, New Delhi
This brief review presents a concise literature account of the metal-catalyzed cross-coupling reactions of halomaleic anhydrides and halomaleimides leading to significant synthetic and natural products. Metal-catalyzed Heck, Suzuki-Miyaura, Stille-Migita, Negishi, Hiyama, and Sonogashira cross-coupling reactions with palladium as the key element are discussed. The metal-catalyzed exchange of a vinylic leaving group by a carbon nucleophile, the SNV reaction, gives a diverse range of bioactive natural and unnatural products.
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