4.5 Article

Convenient Methods to Access Chiral Camphanyl Amine Derivatives by Sodium Borohydride Reduction of D-(-)-Camphorquinone Imines

期刊

SYNTHESIS-STUTTGART
卷 44, 期 20, 页码 3185-3190

出版社

GEORG THIEME VERLAG KG
DOI: 10.1055/s-0032-1317012

关键词

sodium borohydride; chirality; reduction; diimines; diamines

资金

  1. CSIR (New Delhi) for a research fellowship
  2. DST through a J.C. Bose National Fellowship grant
  3. UGC under the University of Potential for Excellence (UPE)
  4. Center for Advanced Studies (CAS)
  5. UGC-Chemistry Networking Center

向作者/读者索取更多资源

D-(-)-Camphorquinone imines prepared using methanolic ammonia, ethanol amine, exo-(-)-bornylamine, ethylene diamine, propylene diamine, and trans-(R, R)-1,2-diaminocyclohexane, upon reduction using sodium borohydride in methanol, give the corresponding chiral exo amino alcohol and diamine derivatives in good yields (75-95%).

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