期刊
SYNTHESIS-STUTTGART
卷 -, 期 15, 页码 2407-2414出版社
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0030-1260101
关键词
iodocyclization; quinolin-2-ones; alkynes; heterocycles; spiro compounds
资金
- CSIR
- UGC
A general method has been developed for the selective synthesis of 3-iodoquinolin-2-ones and spiro[4.5]trienes via intramolecular iodocyclization of N-ortho-substituted aryl)-3-phenylpropiolamides using iodine/cerium(IV) ammonium nitrate reagent under mild reaction conditions. The electronic effect of ortho-substituents electron-rich and electron-deficient group) triggers the two different reaction pathways resulting to iodocyclized quinolin-2-one and ipso-iodocyclized spiro-type compounds.
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