期刊
SYNTHESIS-STUTTGART
卷 -, 期 9, 页码 1405-1427出版社
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0029-1216632
关键词
cross-coupling; catalysis; halides; transition metals; site selectivity
This review highlights transition-metal-catalyzed cross-coupling reactions in which one of the halogen atoms (or pseudohalogen groups) of di- or polyhalogenated compounds is converted site-selectively into another group. The compounds are categorized as halogenated alkenes, heteroarene derivatives, benzene derivatives, and alkanes. Enantioselective cross-coupling of substrates having two enantiotopic halo groups is also described.
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