期刊
SYNTHESIS-STUTTGART
卷 -, 期 9, 页码 1531-1544出版社
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0028-1088045
关键词
amines; Lewis bases; organocatalysis; transfer hydrogenation; trichlorosilane
资金
- Deutsche Forschungsgemeinschaft [SPP 1179]
We report structural and mechanistic studies on the organocatalytic asymmetric transfer hydrogenation of ketimines with trichlorosilane. Amines were obtained in good yields and moderate enantioselectivities. Both experiment and computation were utilized to provide an improved understanding of the mechanism.
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