4.4 Article

Visible Light Induced Photocatalytic Conversion of Enamines into Amides

期刊

SYNLETT
卷 25, 期 11, 页码 1626-1628

出版社

GEORG THIEME VERLAG KG
DOI: 10.1055/s-0034-1378205

关键词

photochemistry; catalysis; enamines; amides

资金

  1. National Science Foundation of China [20872004, 20972008]
  2. National 973 Project from the State Ministry of Science and Technology of China
  3. Shenzhen Bureau of Science, Technology and Information
  4. Shenzhen Shuang Bai Project

向作者/读者索取更多资源

A series of enamines were photocatalytically cleaved to produce amide products under simple visible-light irradiation from a 45 W household light bulb. Mechanistically, the reactions appear to involve photosensitized formation of a singlet oxygen intermediate and a subsequent [2+2] cycloaddition event.

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