期刊
SYNLETT
卷 25, 期 4, 页码 477-490出版社
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0033-1340482
关键词
squaraines; materials science; conjugation; cyanines; heterocycles
资金
- Fondazione Cariplo [2010-0564, 2011-1832]
- Ministero dell'Istruzione dell'Universita e della Ricerca Italia [MIUR-FIRB RBNE033KMA]
- Consorzio Interuniversitario Nazionale di Scienza e Tecnologia dei Materiali (INSTM-PRISMA)
The purpose of this account is to give an overview of the wide variety of available structures that share the common name squaraines', with particular attention to the results achieved by our group in the last ten years. The first section of the report is an introduction and a description of the motivation for our interest in squaraine compounds. The second section includes a survey of the history of squaraines in the scientific literature, and the third section contains a general description of their synthesis and reactivity, together with reports on our direct experiences of their use in materials science, with a focus on squaraines in third-generation photovoltaics, nonlinear optics, and photodynamic therapy. In all of the cases, we highlight the establishment of structure-property relationships directed at the design of materials with improved properties. 1Introduction and Motivation 2Squaraines in the Scientific Literature 3Synthesis of Squaraine Compounds 3.1Symmetric Derivatives 3.2Nonsymmetric Derivatives 3.3Bis-squaraines 3.4Core-Substituted Squaraines 3.5Squaraines That We Have Not (Yet) Tried To Make 4Conclusion
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