期刊
SYNLETT
卷 -, 期 9, 页码 1343-1348出版社
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0031-1290957
关键词
N-heterocyclic carbenes; NHC-CO2 adducts; carbon dioxide; epoxides; cyclic carbonates
资金
- Jiangsu Education Committee [08QLT001, 08QLD006]
- SRF for ROCS, SEM
- PAPD
- NSFC [21172188, 21071121]
- 333 project for the cultivation of high-level talents [33GC10002]
A very simple and convenient method toward coupling of CO2 with epoxides catalyzed by NHC/ZnBr2 has been developed. This catalytic system exhibits excellent activity and selectivity in the cycloaddition reactions of CO2 to terminal epoxides. The reactions can even be carried out under CO2 pressure as low as 0.05 MPa and give carbonates in high yields.
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