期刊
SYNLETT
卷 -, 期 5, 页码 778-782出版社
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0031-1290364
关键词
organoboron dye; conjugated polymer; BODIPY; near-infrared
资金
- National Natural Science Foundation of China [21074054, 51173078, 21172106]
- National Basic Research Program of China [2010CB923303]
Three novel BODIPY-based conjugated polymers could be synthesized via palladium-catalyzed Sonogashira coupling reaction. Compared with BODIPY model derivatives, the polymers can emit in the range from deep-red to near-infrared region with emission spectral maxima at lambda = 640-660 nm and exhibit moderate fluorescent quantum yield from 0.23 to 0.26. Density functional theory (DFT) calculations are performed on three polymers repeat units, and HOMO and LUMO energy levels of the conjugated polymers are estimated.
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