期刊
SYNLETT
卷 -, 期 3, 页码 389-392出版社
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0031-1290137
关键词
benzyne; dihydroquinolines; azadienes; cycloaddition; 3-O-methylviridicatin
资金
- National Institutes of Health [1 R15 GM088780-01]
The synthesis of aryl-substituted 1,4-dihydroquinolines can be achieved using a [4+2] cycloaddition between benzyne and various aryl-substituted 1-azadienes. The conditions are tolerated by N-aryl-, alkyl-, tosyl-, and tert-butoxycarbonyl-protected 1-azadienes. A short synthesis of the fungal metabolite 3-O-methylviridicatin is reported.
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