期刊
SYNLETT
卷 -, 期 9, 页码 1394-1396出版社
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0031-1290960
关键词
aryldiazonium salts; pinacol arylboronate; borylation; Sandmeyer reaction; 4-carboxylphenylboronate ester
资金
- Natural Science Foundation of Jiangshu Province [BK2011813]
Copper(I)-catalyzed cross-coupling reactions of aryl diazonium salts with bis(pinacolato)diboron can proceed smoothly in the water phase at room temperature to give the corresponding arylboronate esters in good to high yields. The Sandmeyer-type borylation not only provides direct access to arylboronates bearing halo and acidic substituents, but also achieves a green borylation process.
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