期刊
SYNLETT
卷 -, 期 19, 页码 2749-2752出版社
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0032-1316555
关键词
palladium; C-H activation; alkenes; acetonitrile; pyridine
资金
- National Basic Research Program of China [973-2009CB825300]
- National Natural Science Foundation of China [20972175, 20923005, 21121062]
- Chinese Academy of Science
A palladium-catalyzed oxidative arylalkylation of unactivated alkenes involving dual C-H bond cleavage of arene and acetonitrile was developed. This reaction was promoted by pyridine as a ligand, and the ratio of palladium to pyridine is vital for this transformation. A series of nitrile-containing indolines were efficiently provided in moderate to good yields.
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