期刊
SYNLETT
卷 -, 期 9, 页码 1243-1246出版社
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0030-1259955
关键词
organocatalysis; domino reaction; amines; asymmetric reduction; Hantzsch ester
资金
- DFG [SPP 1179]
A catalytic enantioselective synthesis of a new class of quinolizidines and indolizidines is presented. An asymmetric Bronsted acid catalyzed hydrogenation cascade as well as a sequential Bronsted acid/metal catalyzed hydrogenation protocol of 2-substituted quinolines yields benzofused quinolizidines and indolizidines in good yields with high diastereo- and enantioselectivities.
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