期刊
SYNLETT
卷 -, 期 19, 页码 2887-2890出版社
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0030-1259039
关键词
palladium catalyst; allylic amination; trifluoromethyl group; chiral allylic amine; kinetic resolution
We succeeded in the regioselective synthesis of chiral trifluoromethyl group substituted allylic amines from chiral allyl acetate using two types of palladium catalysts. Furthermore, we found that the kinetic resolution had occurred during the isomerization step from the gamma-type product to the alpha-type product by the [Pd(C3H5)(cod)]BF4/(S)-BINAP catalyst.
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