4.7 Article

Surface engineering analysis of detonation-gun sprayed Cr3C2-NiCr coating under high-temperature oxidation and oxidation-erosion environments

期刊

SURFACE & COATINGS TECHNOLOGY
卷 206, 期 2-3, 页码 530-541

出版社

ELSEVIER SCIENCE SA
DOI: 10.1016/j.surfcoat.2011.07.077

关键词

High-temperature oxidation; Oxidation-erosion; Coatings; Cr3C2-NiCr; D-gun spray

资金

  1. Department of Science and Technology, New Delhi (India) [SR/FTP/ETA-06/06]

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Detonation-gun (D-gun) spray technology is a novel coating deposition process which is capable of achieving very high gas and particle velocities approaching 4-5 times the speed of sound. This process provides the possibility of producing high hardness coatings with strong adherence. In the present study, this technique has been used to deposit Cr3C2-NiCr coating on T22 boiler steel. Investigations on the behaviour of this coating subjected to high-temperature oxidation in air and oxidation-erosion in actual boiler environment at 700 +/- 10 degrees C under cyclic conditions have been carried out. The weight change technique was used to establish the kinetics of oxidation. X-ray diffraction (XRD), field emission-scanning electron microscopy/energy-dispersive spectroscopy (FE-SEM/EDS) and EDS elemental mapping techniques were used to analyse the oxidation/oxidation-erosion products. The uncoated boiler steel suffered from a catastrophic degradation in the form of intense spalling of the scale in both the environments. The Cr3C2-NiCr coating showed good adherence to the boiler steel during the exposures with no tendency for spallation of its oxide scale. (C) 2011 Elsevier B.V. All rights reserved.

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