4.5 Article

Photoconversion from UV-to-yellow in Mn doped zinc silicate nanophosphor material

期刊

SUPERLATTICES AND MICROSTRUCTURES
卷 75, 期 -, 页码 89-98

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ACADEMIC PRESS LTD- ELSEVIER SCIENCE LTD
DOI: 10.1016/j.spmi.2014.07.021

关键词

Sol-gel; Zn2SiO4:Mn; Nanophosphors; Luminescence; Optical materials

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A novel synthesis process of Mn doped beta-Zn2SiO4 yellow nano-phosphors based on sol gel method is presented. These samples were prepared by a simple solid-phase reaction under natural atmosphere at 1500 degrees C after the incorporation of ZnO:Mn nanopartides, in silica monolith. XRD showed the formation of zinc silicate beta-phase, which shows yellow luminescence. In addition, the as-synthesized beta-Zn2SiO4:Mn2+ nanophosphor exhibited intensive broad emission around 574 nm, which was attributed to the T-4(1)-(6)A(1) transition in Mn2+ ions. An exponential fitting analysis has been employed to obtain the lifetime of this yellow emission (574 nm), the average lifetime was found to be 13 ms. The luminescence properties of our nanophosphors were characterized by excitation and emission spectra as well as luminescence decay. (C) 2014 Elsevier Ltd. All rights reserved.

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