Article
Chemistry, Applied
Xiu-Mei Du, Jun-Wei Ma, Qian-Li Li, Shuang Cheng, Yu Cui, Chun-Lin Ma
Summary: Five triorganotin (IV) complexes were prepared and characterized, and their anticancer activities were investigated. Complexes 1 and 3-5 showed superior anticancer activity, and complex 1 also exhibited antimetastatic ability.
APPLIED ORGANOMETALLIC CHEMISTRY
(2023)
Article
Chemistry, Inorganic & Nuclear
Shuai Chen, Ru-Fen Zhang, Qiang Guo, Jia-Jia Nie, Qian-Li Li, Shuang Cheng, Chun-Lin Ma
Summary: Four novel 3,5-bifluorobenzenetelluronic triorganotin(IV) esters have been synthesized and characterized, showing different structural forms and cytotoxicity against human tumor cell lines. The compounds could quench the intrinsic fluorescence of BSA, suggesting potential biological applications.
INORGANIC CHEMISTRY COMMUNICATIONS
(2021)
Article
Chemistry, Multidisciplinary
Mehdi Elsayed Moussa, Tobias Kahoun, Christian Marquardt, Matthias T. Ackermann, Oliver Hegen, Michael Seidl, Alexey Y. Timoshkin, Alexander V. Virovets, Michael Bodensteiner, Manfred Scheer
Summary: This article reports an unprecedented family of substituted anionic derivatives of pnictogenylboranes. By reacting various combinations of H2E'-BH2-NMe3 (E'=P, As) with pnictogen-based nucleophiles MER1R2 (E=P, As; R1=H, R2=Bu-t; R1=R2=Ph; M=Na, K), unsymmetrical and symmetrical products were isolated. Furthermore, the thermodynamics of the reaction pathways were evaluated by quantum chemical computations.
CHEMISTRY-A EUROPEAN JOURNAL
(2023)
Article
Biochemistry & Molecular Biology
Ewa Wagner-Wysiecka, Paulina Szulc, Elzbieta Luboch, Jaroslaw Chojnacki, Pawel Sowinski, Katarzyna Szwarc-Karabyka
Summary: This study presents the preparation and characterization of products resulting from the photochemical and thermochemical rearrangements of certain azoxybenzocrown compounds. The structures of these compounds were determined using various spectroscopic methods, and their ability to bind and recognize metal cations was also investigated.
Article
Chemistry, Inorganic & Nuclear
Ravi Shankar, Priyanka Chauhan, Ekta Jakhar, Archishmati Dubey, Gabriele Kociok-Kohn
Summary: An intensive study on organotin cations with weakly coordinating trifluoromethanesulfonate/arylsulfonate has provided crucial insights into their stability, structural aspects, and catalytic role. The chemistry involving alkanesulfonate ligands remains incomplete due to the presence of strong Sn-O bond. In this study, the scope of diorganostannates, [n-Bu4N][R2Sn(OSO2R1)3] (R = n-Bu, R1 = Me(1), Et(2); R = Ph, R1 = Me(3)), as reactive substrates in the presence of adventitious water was investigated, leading to the formation of [n-Bu2SnOH(OSO2Me)] (4), [n-Bu2Sn(H2O)4][n-Bu4N][OSO2Et]3 center dot H2O (5), and [Ph2Sn(H2O)4][n-Bu4N]2[OSO2Me]4 (6). The crystallographic studies of these compounds reveal their structural identity and the role of alkanesulfonate anions in the formation of supramolecular assemblies.
INORGANIC CHEMISTRY
(2023)
Article
Chemistry, Applied
Tushar S. Basu Baul, Maheswara Rao Addepalli, Andrew Duthie, Priya Singh, Biplob Koch, Hans Gildenast, Ulli Englert, Iran Rojas-Leon, Herbert Hopfl
Summary: In this study, three organic hydroxy-carboxylic acids with different alkyl groups were reacted with triorganotin precursors to obtain 10 complexes with varying solid-state structures. The complexes showed different coordination polymers based on the substituents attached to the tin atoms and ligands, and demonstrated potential antiproliferative activity against cervical cancer cells.
APPLIED ORGANOMETALLIC CHEMISTRY
(2021)
Article
Biochemistry & Molecular Biology
Pavel S. Lemport, Valentine S. Petrov, Petr I. Matveev, Uliana M. Leksina, Vitaly A. Roznyatovsky, Igor P. Gloriozov, Alexandr V. Yatsenko, Viktor A. Tafeenko, Pavel V. Dorovatovskii, Viktor N. Khrustalev, Gleb S. Budylin, Evgeny A. Shirshin, Vitaliy Yu. Markov, Alexey A. Goryunkov, Vladimir G. Petrov, Yuri A. Ustynyuk, Valentine G. Nenajdenko
Summary: The reaction of acyl chlorides derived from 1,10-phenanthroline-2,9-dicarboxylic acids with piperazine allows the preparation of 24-membered macrocycles in good yield. These new macrocyclic ligands have promising coordination properties towards f-elements, particularly Am and Eu. They exhibit higher extraction efficiency for Am(III) compared to calixarene-type extraction, and the composition of the macrocycle-metal complex with Eu(III) has been investigated.
INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES
(2023)
Article
Chemistry, Physical
Bibi Hanifa, Muhammad Sirajuddin, Edward R. T. Tiekink, Ishaq Khan, Maciej Kubicki, Ahmed Bari
Summary: In this study, a series of new tri-organotin(IV) carboxylate complexes were validated using various techniques. The compounds exhibited antimicrobial activity and anticancer potential through interactions with DNA, and they also met the requirements of drug-likeness.
JOURNAL OF MOLECULAR STRUCTURE
(2022)
Article
Chemistry, Organic
Liubo Li, Anton El Khoury, Brennan O'Neil Clement, Carolyn Wu, Patrick G. Harran
Summary: In this study, polyhydroxylated chains reminiscent of lactonized deoxoKdn type sugars were synthesized through sequential organocatalytic additions. Functionalized chain precursors to portimine were assembled via further homologation and acylation reactions. This work provides advanced intermediates useful for exploring the biosynthesis and de novosynthesis of portimine.
Article
Chemistry, Organic
Pronay Das, D. Srinivasa Reddy
Summary: Resorcyclic Acid Lactones (RALs) are fungal secondary polyketides with broad biological activities and synthetic importance. The total synthesis of (R)-penicimenolide A, (R)-trans-resorcyclide, and (R)-dihydroresorcyclide was reported, utilizing ring closing metathesis as a key step in constructing the core macrolactone scaffold.
Article
Chemistry, Inorganic & Nuclear
Emily Hoffer, Brian P. Niebuhr, Kristof Pota, Timothy M. Schwartz, Marianne E. Burnett, Timothy J. Prior, Horst Puschmann, Kayla N. Green
Summary: The growth of the library of tetraaza macrocyclic pyridinophane ligands offers potential for treating neurodegenerative diseases. This study discovered a helical structure formed by (PyN3Cu)-Py-OH at pH 6.5, driven by pH-dependent keto-enol tautomerization and perchlorate templating. This finding highlights the importance of tautomerization and pH in pyridinophane complexes.
INORGANICA CHIMICA ACTA
(2022)
Article
Chemistry, Inorganic & Nuclear
Thomas Hoellerhage, Thomas P. Spaniol, Ulli Englert, Jun Okuda
Summary: In this study, the synthesis of a hydride cation in the presence of Me(6)HACO was attempted, and the hydrogenolysis of the benzyl cation was investigated. The results showed that the benzyl cation undergoes hydrogenolysis to form toluene and a hydride species.
INORGANICA CHIMICA ACTA
(2022)
Article
Biochemistry & Molecular Biology
Stefano Volpi, Aishling Doolan, Laura Baldini, Alessandro Casnati, Peter B. Crowley, Francesco Sansone
Summary: This study tested a rigid cone calix[4]arene with anionic alanine units as a ligand for cytochrome c, and NMR spectroscopy revealed the presence of two binding sites at lysine residues.
INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES
(2022)
Article
Chemistry, Inorganic & Nuclear
Yasemin Baygu, Inci Capan, Rifat Capan, Matem Erdogan, Yaser Acikbas, Nilgun Kabay, Yasar Gok, Kemal Buyukkabasakal
Summary: A novel phthalonitrile with a 26-member tetraoxadithia macrocycle moiety was synthesized and cyclomerized to obtain a new zinc(II) phthalocyanine. Characterization of the novel phthalocyanine and precursor compounds was conducted using various techniques. Langmuir-Blodgett (LB) thin films were fabricated using the 26-membered phthalocyanine to investigate its gas sensing properties. The sensor parameters and the thickness effect on the gas sensing mechanism were examined using Quartz Crystal Microbalance (QCM) technique. Experimental measurements of QCM kinetic were validated using a nonlinear autoregressive with exogenous input neural network.
INORGANIC CHEMISTRY COMMUNICATIONS
(2023)
Article
Chemistry, Multidisciplinary
Niloufar Dorosti, Soghra Nikpour, Foroogh Molaei, Maciej Kubicki
Summary: A two-component cocrystal consisting of N-isonicotinyl, N',N''-bis(hexamethylenyl) phosphoric triamide and triphenyltin(IV) chloride in a 1:1 stoichiometric ratio was reported. Crystallographic information and theoretical calculations were used to understand the structure-directing interactions, revealing the presence of two crystallographically independent molecules for each component and a formation of centrosymmetric hydrogen-bonded dimers. The significance of non-covalent interactions in the stability of the crystalline structure was highlighted, with the cocrystal showing higher reactivity compared to 4-PCAPh.
Article
Chemistry, Multidisciplinary
Xiaoqing Wang, Qingsong Liu, Hui Yan, Zhipeng Liu, Mingguang Yao, Qingfu Zhang, Shuwen Gong, Weijiang He
CHEMICAL COMMUNICATIONS
(2015)
Article
Chemistry, Inorganic & Nuclear
Qing-Fu Zhang, Jing-Jing Zhang, Ming-Yuan Lei
JOURNAL OF COORDINATION CHEMISTRY
(2016)
Article
Multidisciplinary Sciences
Mei-Ju Niu, Zhen Li, Guo-Liang Chang, Xiang-Jin Kong, Min Hong, Qing-fu Zhang
Article
Chemistry, Multidisciplinary
Fang Liu, Jing-Jing Zhang, Ming-Yuan Lei, Qing-Fu Zhang
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY
(2015)
Article
Chemistry, Multidisciplinary
Qingxia Yao, Yerong Fan, Zhan Wang, Wenzeng Duan, Suna Wang, Yunwu Li, Dacheng Li, Qingfu Zhang, Yuchang Du, Jianmin Dou
Article
Optics
Qingfu Zhang, Mingyuan Lei, Jingjing Zhang, Yang Shi
JOURNAL OF LUMINESCENCE
(2016)
Article
Chemistry, Inorganic & Nuclear
Qingfu Zhang, Mingyuan Lei, Hui Yan, Jinyun Wang, Yang Shi
INORGANIC CHEMISTRY
(2017)
Article
Chemistry, Multidisciplinary
Qingfu Zhang, Mingyuan Lei, Fang Kong, Yan Yang
CHEMICAL COMMUNICATIONS
(2018)
Article
Chemistry, Multidisciplinary
Qingfu Zhang, Aijing Geng, Haina Zhang, Falu Hu, Zhang-Hui Lu, Dezhi Sun, Xilian Wei, Chunlin Ma
CHEMISTRY-A EUROPEAN JOURNAL
(2014)
Article
Chemistry, Inorganic & Nuclear
Qingfu Zhang, Haina Zhang, Aijing Geng, Suna Wang, Chong Zhang
JOURNAL OF SOLID STATE CHEMISTRY
(2014)
Article
Chemistry, Inorganic & Nuclear
Mingyuan Lei, Xiaohe Wang, Yang Shi, Qingfu Zhang
JOURNAL OF CLUSTER SCIENCE
(2020)
Article
Chemistry, Physical
Xiuting Gao, Xiaohe Wang, Weixiang Lv, Ning Wang, Ming Yang, Qingfu Zhang
Summary: Excessive release of inorganic and organic hazardous chemical pollutants poses a great threat to public health and sustainable development. In this work, a new coordination polymer with good water stability and luminescent property was designed and synthesized. It serves as a multi-responsive luminescent sensor for sensitive, selective and recyclable detection of Fe3+, Cr2O72-, and FZD in aqueous solution. The luminescent quenching mechanisms were also discussed.
JOURNAL OF MOLECULAR STRUCTURE
(2022)
Article
Chemistry, Inorganic & Nuclear
Mingyuan Lei, Xiaohe Wang, Tianjun Zhang, Yang Shi, Jinghong Wen, Qingfu Zhang
Summary: This study developed a homochiral metal-organic framework (HMOF) that could be used for the detection and separation of chiral drugs. By encapsulating Eu3+ cations, a dual-luminescent composite material was synthesized with high chemical stability and enantioselectivity. This work provides a simple strategy for the preparation of Ln(III)-incorporated HMOF composite materials for simultaneous enantioselective detection and separation of chiral drugs.
INORGANIC CHEMISTRY
(2022)
Article
Chemistry, Multidisciplinary
Xiuting Gao, Xiaohe Wang, Miaomiao Feng, Ming Yang, Qingfu Zhang
Summary: A new luminescent Zn-MOF material was successfully synthesized for the detection of Al3+ and antibiotics pollutants in water, demonstrating excellent water stability and luminescent performance. This material can serve as a dual-responsive chemical sensor for turn-on and turn-off luminescent detection of Al3+ and SNT in aqueous media, showing great potential for practical applications in monitoring metal ions and antibiotics pollutants in environmental water matrices.
Article
Chemistry, Inorganic & Nuclear
Xiaohe Wang, Mingyuan Lei, Tianjun Zhang, Qingfu Zhang, Rufen Zhang, Ming Yang
Summary: The study introduced a new luminescent MOF for efficient detection of harmful pollutants in water, suggesting promising environmental monitoring applications.
DALTON TRANSACTIONS
(2021)