Article
Chemistry, Physical
Mohamed A. Kolmangadi, Arda Yildirim, Kathrin Sentker, Martin Butschies, Andrea Buehlmeyer, Patrick Huber, Sabine Laschat, Andreas Schoenhals
Summary: The molecular mobility and conductivity of four bent shaped tetramethylated guanidinium based ionic liquid crystals with varying head group configuration and alkyl chain length were investigated using BDS and SHS techniques. Different relaxation processes and conductivity contributions were observed for the different ILCs, which may be related to their distinct molecular structures and formation mechanisms.
JOURNAL OF MOLECULAR LIQUIDS
(2021)
Article
Chemistry, Physical
P. Romero-Hasler, E. A. Soto-Bustamante, C. Parry-Mix, B. I. Ostrovskii
Summary: A series of 4-alkyloxyphenyl 4-(6-(methacryloyloxy)hexyloxy))benzoate monomers were synthesized and characterized. The study reveals the presence of both the nematic and monolayered orthogonal smectic A phase in the M6En series. It was found that monomers with a terminal chain length of five to twelve carbon atoms exhibit a wide temperature range of stable smectic A phase and a narrow intervening nematic phase at higher temperatures. The phase diagram and mesogenic properties of the M6En series are discussed in relation to the molecular structure of these monomers.
JOURNAL OF MOLECULAR LIQUIDS
(2023)
Article
Chemistry, Physical
Pradip K. Bhowmik, Omar Noori, Si L. Chen, Haesook Han, Michael R. Fisch, Christina M. Robb, Aaron Variyam, Alfonso Martinez-Felipe
Summary: A series of asymmetric viologen bistriflimide salts with short and long alkyl chains were synthesized by metathesis reaction, exhibiting high thermal stability and ionic conductivity, suggesting potential use as electrolytes.
JOURNAL OF MOLECULAR LIQUIDS
(2021)
Article
Nanoscience & Nanotechnology
Guan-Syuan Li, Chih-Chien Hung, Yun-Chi Chiang, Yan-Cheng Lin, Yun-Fang Yang, Wei-Chen Yang, Hao-Chi Yen, Chun-Kai Chen, Li-Che Hsu, Wen-Chang Chen
Summary: This study investigates the use of rod-like molecules with liquid crystalline phase transitions for high-performance photonic FET memory. By optimizing the alkyl chain length, the study achieved volatility transition and improved performance in terms of charge storage and charge tunneling, resulting in a superior ON/OFF current ratio and retention time. The results demonstrate the great potential of utilizing rod-like molecules with smectic liquid crystalline phase and highly ordered orientation for developing advanced photonic FET memory.
ADVANCED ELECTRONIC MATERIALS
(2022)
Article
Chemistry, Multidisciplinary
Kanubhai D. Katariya, Kiran J. Nakum, Mohamed Hagar
Summary: A series of 12 new asymmetric fluorinated azobenzene-Schiff Bases, Aa-l, with different alkyloxy groups varying in carbon chain length from n = 2 to n = 18 at one end and polar atoms like chlorine and fluorine on an aromatic ring at position 3 and 4 were synthesised and studied for their mesomorphic behavior, optical properties, and thermal stability. The compounds exhibited characteristic textures of smectic A phase, and their photo-isomerisation property under UV light was also investigated. Additionally, density functional theory (DFT) calculations were carried out to analyze the thermal and geometrical parameters of the mesogens and understand the relationship between structural parameters and mesomorphic behavior.
Article
Chemistry, Applied
Aleksandra Torbica, Ilinka Pecinar, Steva Levic, Miona Belovic, Mirjana Jovicic, Zora Dajic Stevanovic, Viktor Nedovic
Summary: Barley, rye, triticale, oat, sorghum and millet flours were analyzed after roasting or extrusion treatment to investigate the structural changes in starch and protein molecules. Extrusion treatment led to more extensive changes in both starch and protein structure compared to roasting treatment. The changes included alterations in protein secondary structure and disulfide bond conformation, as well as complete gelatinization and amylose-lipid complex formation in the starch structure. The rheological properties of the doughs were also affected by these structural changes, with extruded doughs exhibiting higher mechanical resistance.
FOOD HYDROCOLLOIDS
(2023)
Article
Physics, Multidisciplinary
A. Deptuch, A. Lelito, M. Urbanska
Summary: Polarizing optical microscopy was used to investigate the crystallization behavior of the 3F6FPhF6 compound, which exhibits the smectic C* and smectic C-A* phases, under isothermal and non-isothermal conditions. A large hysteresis in the phase transition was observed. The kinetics of non-isothermal crystallization were analyzed using a continuous cooling transition diagram, and the cooling rate required for partial vitrification was estimated. The relationship between the thermodynamic driving force of crystallization and the thermal energy of translational degrees of freedom was found to strongly influence crystallization.
ACTA PHYSICA POLONICA A
(2023)
Article
Physics, Multidisciplinary
Jack Paget, Una Alberti, Marco G. Mazza, Andrew J. Archer, Tyler N. Shendruk
Summary: In this study, a phenomenological Landau theory based on a complex-tensor order parameter is developed to describe the features of lamellar liquid crystals. This theory considers the local degree of lamellar ordering, layer displacement, and orientation of the layers, and resolves some issues in previous models.
JOURNAL OF PHYSICS A-MATHEMATICAL AND THEORETICAL
(2022)
Review
Polymer Science
Yong Ye, Li Guo, Tingjun Zhong
Summary: Polymer-stabilized liquid crystals (PSLCs) are versatile materials with polymer networks providing anchoring energy for liquid crystals. This review details various improvements in PSLCs, including polymer-stabilized nematic, cholesteric, blue phase, smectic, ferroelectric, and antiferroelectric liquid crystals. PSLCs offer multiple functionalities, such as reorientation in smart windows and manual tuning of reflection bandwidth in broadband reflectors. PSBPLCs open up new possibilities for displays, modulators, sensors, lasers, lenses, and photonics applications. Polymer networks in PSFLCs or PSAFLCs enhance grayscale memories for flexible displays and energy-saving smart cards. The remaining challenges and research opportunities in PSLCs are also discussed.
Article
Chemistry, Multidisciplinary
Chenjing Yang, Li Chen, Rui Zhang, Dong Chen, Laura R. Arriaga, David A. Weitz
Summary: The interactions between liquid crystals and amphiphilic molecules at the interface are crucial for the development of molecular sensors. This paper demonstrates that the development of smectic liquid crystal ordering induces local high-density distributions of amphiphilic phospholipids at the liquid crystal/water interface. The transition of phospholipids from liquid-expanded to liquid-condensed phases in response to the smectic ordering leads to increased surface tension at the interface.
CHINESE CHEMICAL LETTERS
(2022)
Article
Chemistry, Physical
Shigemasa Nakasugi, Sungmin Kang, Tso-Fu Mark Chang, Takaaki Manaka, Hiroki Ishizaki, Masato Sone, Junji Watanabe
Summary: A dimeric molecule di-5(3FM-C4T) with fluoro-substituted mesogenic cores forms three different phases: ferroelectric nematic (N-F), ferroelectric smectic-A (SmAP(F)), and polarisotropic (Iso(P)). The N-F phase consists of U-shaped molecules behaving like polar rod-like molecules, while the SmAP(F) phase is formed by bent-shaped molecules. The highest temperature Iso(P) phase retains a polar structure and possibly some polar aggregation of molecules. All three polar phases exhibit a dielectric mode at around 100 Hz, resulting in a high dielectric constant of over 8000.
JOURNAL OF PHYSICAL CHEMISTRY B
(2023)
Article
Chemistry, Physical
Alexander Krivoshey, Vadim Mikhailenko, Ekaterina Popova, Alexander Fedoryako, Olga Vashchenko, Hanna Vlasenko, Valerii Vashchenko
Summary: This paper presents the design and study of fluorinated and non-fluorinated p-terphenyl-containing symmetric tetraesters as chiral components in ferroelectric liquid crystal materials. The new chiral components exhibit a short helix pitch and large spontaneous polarization at low concentrations. The effects of the lactate linker, alkyl chains, and fluorine atoms on the properties of the chiral tilted smectic phase are investigated. The results show that the fluorination of the p-terphenyl core has little effect on the helical twisting power, while modifications in the chiral tails can significantly enhance the performance characteristics. The findings have important implications for understanding the role of chiral components in liquid crystal materials and the design of such materials.
JOURNAL OF MOLECULAR LIQUIDS
(2022)
Article
Chemistry, Physical
Hanqing Wu, Hui Tan, Sining Zheng, Hongyu Guo, Fafu Yang
Summary: The influence of symmetric/asymmetric structure on circularly polarized luminescence properties was investigated for the first time in this study. The compounds with symmetric structure exhibited better fluorescence and chiroptical properties compared to the compounds with asymmetric structure.
JOURNAL OF MOLECULAR LIQUIDS
(2022)
Article
Chemistry, Physical
Nan Zhou, Hua Yan, Peibai Wei, Hongyu Guo, Fafu Yang
Summary: Although some AIE-based CPL materials have been developed, it is still challenging to design and synthesize novel AIE-based CPL materials and study the relationship between structure and properties. In this study, a series of novel 1,4-bis(p-cyanostyryl)benzene derivatives 2a, 2b, and 2c were prepared with chiral alkyl chains, and the influence of alkyl chain length on CPL properties was investigated for the first time. Samples 2a, 2b, and 2c showed strong fluorescence and exhibited strong chiroptical properties. The self-assembly in the mesophase resulted in the best chiroptical properties, with sample 2c achieving the highest glum value of 1.6 x 10-2.
JOURNAL OF MOLECULAR LIQUIDS
(2023)
Article
Crystallography
Peter John Tipping, Helen Frances Gleeson
Summary: This paper investigates the electrocaloric potential of ferroelectric liquid crystals as heat-exchanging materials in electrocaloric devices. The field-induced temperature changes of three selected ferroelectric liquid crystal systems are measured using the Maxwell method. The results show that the maximum induced temperature change is 0.37 K, which is currently the highest record in the FLC field, making these materials interesting candidates for electrocaloric applications.
Article
Chemistry, Physical
Debraj Gangopadhyay, Poornima Sharma, Sachin Kumar Singh, Pushkar Singh, Nicolae Tarcea, Volker Deckert, Juergen Popp, Ranjan K. Singh
CHEMICAL PHYSICS LETTERS
(2015)
Article
Chemistry, Multidisciplinary
Sachin Kumar Singh, Vijay Kumar, Hemant Kumar Singh, Priyanka Kanth, Bachcha Singh
Article
Chemistry, Multidisciplinary
Sachin Kumar Singh, Vijay Kumar, Rajib Nandi, Hemant Kumar Singh, Ranjan K. Singh, Bachcha Singh
Article
Chemistry, Multidisciplinary
Hemant Kumar Singh, Sachin Kumar Singh, Rajib Nandi, Madan Kumar Singh, Vijay Kumar, Ranjan K. Singh, D. S. Shankar Rao, S. Krishna Prasad, Bachcha Singh
Article
Spectroscopy
Rajib Nandi, Sachin Kumar Singh, Hemant Kumar Singh, D. S. Shankar Rao, S. Krishna Prasad, Bachcha Singh, Ranjan K. Singh
JOURNAL OF RAMAN SPECTROSCOPY
(2016)
Article
Chemistry, Multidisciplinary
Rajib Nandi, Hemant Kumar Singh, Sachin Kumar Singh, D. S. Shankar Rao, S. Krishna Prasad, Bachcha Singh, Ranjan K. Singh
Article
Chemistry, Multidisciplinary
Sachin Kumar Singh, Madan Kumar Singh, Hemant Kumar Singh, Bachcha Singh
MOLECULAR CRYSTALS AND LIQUID CRYSTALS
(2016)
Article
Chemistry, Analytical
Sachin Kumar Singh, Rajib Nandi, Kirtika Mishra, Hemant Kumar Singh, Ranjan Kumar Singh, Bachcha Singh
SENSORS AND ACTUATORS B-CHEMICAL
(2016)
Article
Spectroscopy
Debraj Gangopadhyay, Sachin Kumar Singh, Poornima Sharma, Hirdyesh Mishra, V. K. Unnikrishnan, Bachcha Singh, Ranjan K. Singh
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
(2016)
Article
Chemistry, Multidisciplinary
Hemant Kumar Singh, Sachin Kumar Singh, Rajib Nandi, D. S. Shankar Rao, S. Krishna Prasad, Ranjan K. Singh, Bachcha Singh
Article
Chemistry, Multidisciplinary
Hemant Kumar Singh, Sachin Kumar Singh, Vijay Kumar, Priyanka Kanth, Kirtika Mishra, Bachcha Singh
MOLECULAR CRYSTALS AND LIQUID CRYSTALS
(2017)
Article
Chemistry, Multidisciplinary
Kirtika Mishra, Sachin Kumar Singh, Bachcha Singh
Article
Chemistry, Physical
Hemant Kumar Singh, Ravindra Kumar Gupta, Sachin Kumar Singh, D. S. Shankar Rao, S. Krishna Prasad, Ammathnadu S. Achalkumar, Bachcha Singh
JOURNAL OF MOLECULAR LIQUIDS
(2019)
Article
Chemistry, Physical
Priyanka Kanth, Hemant Kumar Singh, Vijay Kumar, Sachin Kumar Singh, D. S. Shankar Rao, S. Krishna Prasad, Bachcha Singh
JOURNAL OF MOLECULAR LIQUIDS
(2019)
Article
Chemistry, Multidisciplinary
Priyanka Kanth, Hemant Kumar Singh, Vijay Kumar, Sachin Kumar Singh, D. S. Shankar Rao, S. Krishna Prasad, Bachcha Singh
Article
Spectroscopy
Zh. E. Ozbekova, A. A. Abdyldaev, A. A. Kulmyrzaev
Summary: This study compared two drying methods for cow and yak muscles, finding that freeze drying caused less discoloration. Additionally, analysis of fluorescence spectra allowed for accurate prediction of chemical composition and color characteristics of the muscles.
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
(2024)
Article
Spectroscopy
Leo Mandic, Ivan Ljubic, Iva Dzeba
Summary: In this study, a combined experimental and computational approach was used to investigate the photoexcitation and photodegradation mechanisms of Doxazosin (DOX). The results provide valuable insights into the primary events following the photoexcitation of DOX and its potential applications.
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
(2024)
Article
Spectroscopy
Xiufeng Wang, Yao Jin, Wenhui Ai, Siqi Wang, Zhiqing Zhang, Ting Zhou, Fang Wang, Guodong Zhang
Summary: This study successfully synthesized near infrared fluorescence Ag2S quantum dots (QDs) and developed a dual-mode sensor for sulfide anion using the excellent oxidase-like characteristics of manganese dioxide (MnO2) nanosheets. The sensor showed a wider detection range, higher sensitivity, and shorter reaction time, making it suitable for highly selective detection of sulfide in different concentration ranges.
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
(2024)
Article
Spectroscopy
Yafei Li, Yanming Ma, Chuantao Zheng, Di Yu, Lien Hu, Shuo Yang, Fang Song, Yadan Li, Shuanghai Liu, Zhanrui Zhang, Yu Zhang, Yiding Wang, Frank K. Tittel
Summary: To effectively monitor gas explosion and coal spontaneous combustion in coal mine, an intrinsically safe and explosion-proof dual-gas sensor system was developed for methane (CH4) and carbon monoxide (CO) measurement. The system achieved different measurement ranges using laser scanning and gas cells, and improved stability and accuracy through gas pre-treatment and temperature compensation algorithm.
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
(2024)
Article
Spectroscopy
Pei-Rong Chen, Li-Kang Chu
Summary: In this study, the hydrates of glyoxal were investigated using infrared absorption spectrometry. The results showed that at low concentrations, glyoxal mainly exists as monomeric dihydrate. These findings provide suitable detection windows for further research on the roles of glyoxal and its hydrates in atmospheric and aerosol chemistry, as well as the relevant reaction kinetics.
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
(2024)
Article
Spectroscopy
Nichole O'Neill, Thamires A. Lima, Fabio Furlan Ferreira, Nicolas J. Alvarez, Reinhard Schweitzer-Stenner
Summary: This study determines the main fibril axis of GHG gel-forming fibrils using various techniques and compares the results with simulated data. The analysis suggests that the hydrophobic xz-surfaces of GHG fibrils could be a good target for the adsorption of hydrophobic drugs.
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
(2024)
Article
Spectroscopy
Mengyuan Liu, Hanchuang Zhu, Yikun Fang, Caiyun Liu, Xinke Li, Xiaohui Zhang, Lixue Ma, Kun Wang, Miaohui Yu, Wenlong Sheng, Baocun Zhu
Summary: ABHS is an efficient fluorescent probe that can accurately and sensitively detect Al3+ with strong resistance to interference. It also demonstrates excellent detection and imaging capabilities in complex real samples.
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
(2024)
Article
Spectroscopy
Ahmed S. El-Shafie, Evana Rahman, Yasser Gadelhak, Rehab Mahmoud, Marwa El-Azary
Summary: The recycling of waste mandarin peels into biochar (MRBC) has been used as a high performance and cost-effective adsorbent for treating polluted wastewater effluents. Batch adsorption studies were conducted to analyze the adsorption competency of MRBC on two dyes, methylene blue (MB) and basic fuchsin (BF), either in individual solutions or binary combinations. The results showed that MRBC was capable of effectively removing a high percentage of both dyes. However, the adsorption capacity decreased when the dyes were combined. The cost estimation of MRBC production and wastewater treatment indicated that both were relatively low.
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
(2024)
Article
Spectroscopy
Anindita Bhatta, Jahnabi Upadhyaya, Dipak Chamlagai, Lincoln Dkhar, Pynskhemborlang T. Phanrang, Mohan Rao Kollipara, Sivaprasad Mitra
Summary: Derivatives of thiazole-pyrazole fused benzo-coumarin compounds were synthesized and their photophysical properties were investigated. The synthesized coumarin compounds showed potential as therapeutic agents for Alzheimer's disease, inhibiting acetylcholinesterase activity. The presence of human serum albumin was found to affect the inhibition activity.
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
(2024)
Article
Spectroscopy
Yongwei Duan, Quancheng Liu, Yiju Zhu, Qi Zhang, Xiaohui Duan, Hu Deng, Liping Shang
Summary: In this study, the phase transition of CL-20 was observed using terahertz spectroscopy, and quantum chemical calculations were employed to analyze the vibrations. The results indicated changes in the vibrations of CL-20 before and after phase transition.
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
(2024)
Article
Spectroscopy
Yuefeng Gao, Sai Xu, Baojiu Chen
Summary: This study synthesized Cs2NaInCl6 nanocrystals co-doped with Sb3+ and Tb3+ ions as probes for copper ions detection in lubricating oil. The introduction of Sb3+ effectively reduced the band gap of the host material and enabled energy transfer pathway for Tb3+ emission. The doped Tb3+ ions resulted in the suppression of emission due to electron transfer. The Cs2NaInCl6: 2.5 %Sb3+, 40 %Tb3+ NCs exhibited superior sensitivity and selectivity for copper ions detection.
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
(2024)
Article
Spectroscopy
Yu Liu, Yue Zhang, Changyao Liu, Ce Wang, Baocai Xu, Li Zhao
Summary: A highly sensitive detection platform for heparin was developed using a cationic fluorescent dye (cresyl violet acetate) as a fluorescence probe. The platform demonstrated high selectivity towards heparin and achieved detection in both HEPES solution and serum.
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
(2024)
Article
Spectroscopy
Lopamudra Roy, Nivedita Pan, Susmita Mondal, Ria Ghosh, Md. Nur Hasan, Neha Bhattacharyya, Soumendra Singh, Kallol Bhattacharyya, Arpita Chattopadhyay, Samir Kumar Pal
Summary: The study focuses on the interaction between reactive oxygen species (ROS) and a spectroscopic probe called Rose Bengal (RB), encapsulated in nanoscopic sodium dodecyl sulphate (SDS) micelles and entrapped in microscopic nylon 66 solid matrix. The research demonstrates efficient interaction between ROS and RB-SDS, and investigates the mechanism of hydroxyl radicals generation. Based on these findings, a prototype device utilizing RB embedded in a nylon thin film for quantification of ROS in extracellular fluids and food materials was developed.
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
(2024)
Article
Spectroscopy
Xiaosong Sun, Qihao Cui, Wenyue Dong, Qian Duan, Teng Fei
Summary: Conjugated porous polymers (CPPs) are promising sensing materials and their application in aqueous media is limited. In this study, we synthesized CPPs with porous structure and prepared nanoparticles, enabling efficient photoluminescence sensing of nitroaromatic explosives in aqueous phase.
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
(2024)
Article
Spectroscopy
Maria Cristina Caggiani, Germana Barone, Paolo Mazzoleni
Summary: Raman spectroscopy is commonly used for studying glassy materials in cultural heritage, but it is more difficult to interpret the spectra and apply the technique with portable instruments. In contrast, diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) can be used in archaeometric investigations as it is portable and non-invasive. However, there is limited application of this technique to historical glasses. This exploratory work demonstrates the potential of DRIFTS, in combination with portable X-ray Fluorescence (pXRF) and EDS microanalyses, for studying the composition and alteration of glass samples in cultural heritage.
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
(2024)