4.7 Article

Optical and structural investigation of Dy3+-Nd3+ co-doped in magnesium lead borosilicate glasses

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PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.saa.2013.09.061

关键词

Magnesium lead borosilicate glasses; Dy3+ ions; Energy transfer; Luminescence; FT-IR spectra

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  1. University Grants Commission, Government of India, New Delhi

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MgO-PbO-B2O3-SiO2-Nd2O3-Dy2O3 glasses are prepared by melt-quenching technique. The samples are characterized by X-ray diffraction (XRD), optical absorption, luminescence and Fourier transform infrared (FT-IR) spectral studied. XRD analysis evidently indicates that the prepared samples are fully amorphous nature. From the optical absorption spectra, the bonding environment surrounding the Dy3+ and their energy level scheme in glass network is analyzed. Enhancement of Dy3+ emission by non-radiative energy transfers from Nd3+ has been observed here. The samples emits intensive bluish yellow color from the 4F9/2 -> H-6(15/2), H-6(13/2) transition of Dy3+ ions in these glasses which are nearer to white light and it is also supported by the chromaticity color coordinates. The FT-IR spectra reveal that network connectivity is increased with replacement of bonds B-O-B, Si-O-Si by more resistant B-O-Si bonds with gradually increasing the content of Dy3+ ions in the glass network. Along with spectroscopic parameters some physical parameters like density, refractive index etc. are measured for the glasses. (C) 2013 Elsevier B.V. All rights reserved.

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