期刊
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
卷 115, 期 -, 页码 876-882出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.saa.2013.06.106
关键词
SnO2 loaded ZnO; Photocatalysis; UV-A light; Acid Orange 10; Reusability
类别
资金
- UGC, New Delhi, India [41-288/2012 (SR)]
The SnO2 loaded ZnO (SnO2-ZnO) was successfully synthesized by precipitation-decomposition method. The catalyst was characterized by X-ray diffraction (XRD), high resolution scanning electron microscope (HR-SEM) images, energy dispersive spectrum (EDS), diffuse reflectance spectra (DRS), photoluminescence spectra (PL) and BET surface area measurements. The photocatalytic activity of SnO2-ZnO was investigated for the degradation of Acid Orange 10 (AO 10) in aqueous solution using UV-A light. SnO2-ZnO is found to be more efficient than commercial ZnO, bare ZnO, TiO2-P25 and TiO2 (Merck) at pH 12 for the mineralization of AO 10 dye. The effects of operational parameters such as the amount of photocatalyst, dye concentration, initial pH on photo mineralization of AO 10 dye have been analyzed. The mineralization of AO 10 has been confirmed by chemical oxygen demand (COD) measurements. A degradation mechanism is proposed for the degradation of AO 10 with SnO2-ZnO under UV-A light. This catalyst is found to be reusable. (C) 2013 Elsevier B.V. All rights reserved.
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