期刊
SOLID STATE SCIENCES
卷 12, 期 4, 页码 490-497出版社
ELSEVIER
DOI: 10.1016/j.solidstatesciences.2009.12.013
关键词
Mesoporous film; TiO(2-x)A(y) (A = N, S); Visible-light-response; Photocatalyst
资金
- Beijing Innovation Talent Project
- Beijing education committee
- Beijing New Century Hundred, Thousand and Ten Thousand Talent Project
Mesoporous TiO(2-x)A(y) (A = N, S) thin films were fabricated using thiourea as a doping resource by a combination of sol-gel and evaporation-induced self-assembly (EISA) processes. The results showed that thiourea could serve two functions of co-doping nitrogen and sulfur and changing the mesoporous structure of TiO2 thin films. The resultant mesoporous TiO(2-x)A(y) (A = N, S) exhibited anatase framework with a high porosity and a narrow pore distribution. The formation of the O-Ti-N and O-Ti-S bonds in the mesoporous TiO(2-x)A(y) (A = N, S) were substantiated by the XPS spectra. A new bandgap in visible light region (520 nm) corresponding to 2.38 eV could be formed by the co-doping. After being illuminated for 3 h, methyl orange could be degraded nearly completely by the co-doped sample under both ultraviolet irradiation and visible light illumination. While pure mesoporous TiO2 could only degrade 60% methyl orange under UV illumination and showed negligible photodegradation capability in the visible light range. Furthermore, the photo-induced hydrophilic activity of TiO2 film was improved by the co-doping. The mesoporous microstructure and high visible light absorption could be attributed to their good photocatalytic acitivity and hydrophilicity. (C) 2009 Elsevier Masson SAS. All rights reserved.
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