期刊
SOLID STATE COMMUNICATIONS
卷 146, 期 11-12, 页码 483-486出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.ssc.2008.04.001
关键词
nanostructures; magnetic materials; chemical synthesis
Monodisperse Zn ferrite nanospheres and its Ba substitution nanosheets were successfully prepared by a facile solvothermal method. The size, morphology, and structure of the as-prepared products were investigated in detail by X-ray diffraction (XRD), transmission electron microscopy (TEM), scanning electron microscopy (SEM), high-resolution transmission electron microscopy (HRTEM), and inductively coupled plasma atomic emission spectroscopy (ICP-AES). Magnetic studies revealed that Zn ferrite nanospheres are ferrimagnetic with a saturation magnetization (M-S) of 49.6 emu/g and M-S increased from 49.6 emu/g to 84.2 emu/g when Ba2+ was substituted into Zn ferrite to form BaZn ferrite nanosheets. To explain the variations of morphology and magnetic properties, the strong preferential occupancy of cations in chemically equivalent A and B sites and the metastable cation distribution in nanoparticles are invoked. (C) 2008 Elsevier Ltd. All rights reserved.
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